Author: Du Zhengyin Li Yanchun Wang Fen Zhou Wanwei Wang Jin-Xian
Publisher: Taylor & Francis Ltd
ISSN: 0039-7911
Source: Synthetic Communications, Vol.41, Iss.11, 2011-05, pp. : 1664-1671
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Abstract
The indium-mediated Barbier-type allylation reaction of aldehydes with allyl bromide, which gives corresponding homoallyl alcohols, was investigated. The reaction medium and the effects of substituents were discussed in detail. The results showed that various aldehydes, including aromatic, heterocyclic, and aliphatic aldehydes, with different substituents could all react well with excellent yields of 91–97% in aqueous tetrahydrofuran at room temperature within about 1 h.
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