

Author: Usha J. Umapathy M. J.
Publisher: Taylor & Francis Ltd
ISSN: 0091-4037
Source: International Journal of Polymeric Materials, Vol.58, Iss.8, 2009-08, pp. : 409-421
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Abstract
The di-site phase transfer catalyzed radical polymerization of butyl methacrylate with the phase transfer catalyst N,N'-diheptyl-N,N,N',N'-tetramethyl-1,2-ethanediammonium dibromide (DHTMEDADB) was carried out in an aqueous-organic biphase system at 60 ± 1°C under nitrogeneous atmosphere at fixed pH and ionic strength. A suitable kinetic scheme has been proposed and its significance was discussed. The polymers obtained were investigated and characterized (FTIR, 1H-NMR and XRD studies).
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