Author： Li Dong-Jiao Gao Dong-Zhao Liao Dai-Zheng Jiang Zong-Hui Yan Shi-Ping
Publisher： Taylor & Francis Ltd
ISSN： 0095-8972
Source： Journal of Coordination Chemistry, Vol.57, Iss.17-18, 2004-11, pp. : 1571-1576
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
The synthesis and structure of Pr(III) complex with chelating nitronyl nitroxide radicals of formula [Pr(III)(NIT2Py) 2 (NO 3 ) 3 ] (NIT2Py = 2-(2′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) is reported. Pr(III) is ten-coordinate with three bidentate nitrate anions and two radicals. The radical behaves as a bidentate chelating ligand through one oxygen atom of the nitronyl nitroxide group and one nitrogen atom of a pyridine ring. The electronic spectrum for the complex in THF and magnetic susceptibilities from 77-300 K are reported.
Related content
Access to resources
Recommend
By Wang Li-Ya Zhang Chen-Xi Liao Dai-Zheng Jiang Zong-Hui Yan Shi-Ping
Journal of Coordination Chemistry, Vol. 58, Iss. 11, 2005-07 ,pp. :
By Cui Chun-Xian Zhang Chen-Xi Wang Li-Ya Zhang Yuying
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol. 37, Iss. 3, 2007-04 ,pp. :
By Zhou Jie Du Lin Li Zongze Qiao Yongfeng Liu Jing Zhu Minrong Chen Peng Zhao Qihua
Journal of Coordination Chemistry, Vol. 66, Iss. 12, 2013-06 ,pp. :