Author： Li Daixi Sun Yuxi Liu Shanlin Hua Zezhao
Publisher： Taylor & Francis Ltd
ISSN： 0095-8972
Source： Journal of Coordination Chemistry, Vol.59, Iss.4, 2006-03, pp. : 403-408
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Abstract
The title compound C 28 H 32 N 8 S 4 ClCu has been synthesized, crystallized and characterized by density measurement, element analysis and IR spectra. Its crystal structure has been determined by X-ray diffraction methods. The most interesting structure feature of the complex is that the dihedral angle between the thiourea framework and the benzene ring is 52.03(22)°, the minimal value in the literature. All four bonds around Cu(I) are equivalent, but the six S–Cu–S angles are non-equivalent.
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