Mechanistic studies of reactions of coordination compounds. Some recent highlights

Author: Hubbard Colin   van Eldik Rudi  

Publisher: Taylor & Francis Ltd

ISSN: 0095-8972

Source: Journal of Coordination Chemistry, Vol.60, Iss.1, 2007-01, pp. : 1-51

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Abstract

Detailed kinetics studies of reactions of coordination compounds in solution have been invaluable in determining the relevant reaction mechanisms. A selection of reports that highlights very recent progress in mechanistic investigations of coordination chemistry is presented. The methods and techniques employed in pursuit of these mechanistic goals are referred to mostly through the latest authoritative reports. Reactions chosen for inclusion are classified according to the comprehensive table of contents. In summary, solvent exchange, ligand substitution, redox reactions, some reactions of nitric oxide and a few other reactions, whose mechanisms have been scrutinised, are covered.