Author： Trzesowska-Kruszynska Agata
Publisher： Taylor & Francis Ltd
ISSN： 0095-8972
Source： Journal of Coordination Chemistry, Vol.64, Iss.4, 2011-02, pp. : 663-678
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Abstract
Two new iron(III) coordination compounds with 2-aminobenzothiazole have been prepared and identified as (C6H4NHC(NH2)S)2[FeCl4]Cl(H2O) (1) and (C6H4NHC(NH2)S)3[Fe(C2O4)3](H2O)2 (2). The compounds were characterized by thermogravimetric analysis in conjunction with evolved gases in air and spectroscopic studies. On the basis of quantum-mechanical calculations the interplay between two non-covalent interactions in 1, anion ··· π and ion-pair interactions, was analyzed.
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