2,2′-Bipyridyl-acetylphenolato mixed ligand copper(II) complexes: syntheses, characterizations and catalytic activity in styrene epoxidation

Author： Shit Shyamapada   Yadava Umesh   Saha Debraj   Fröhlich Roland  

Publisher： Taylor & Francis Ltd

ISSN： 0095-8972

Source： Journal of Coordination Chemistry, Vol.66, Iss.1, 2013-01, pp. : 66-76

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

Two copper(II) complexes, [Cu(bipy)(5-Br-2-hap)(ClO4)]2 (1) and [Cu(bipy)(2-hap)(ClO4)] (2) (where bipy = 2,2′-bipyridine, 5-Br-2-hap = 5-bromo-2-hydroxyacetophenone, 2-hap = 2-hydroxyacetophenone), were synthesized and characterized. The crystal structure of 1 was determined by single crystal X-ray diffraction while 2 was reported earlier. Structural characterization reveals that the presence of bromine in 5-Br-2-hap plays a structure-determining role in dimeric 1 in comparison with the mononuclear 2 where 2-hap was used. Studies of the catalytic potential toward styrene epoxidation in homogeneous system using H2O2 as oxidant reveal that 1 is more efficient than 2 with respect to epoxide selectivity.

Related content

Nuclease activity of mixed ligand complexes of copper(II) with heteroaromatic derivatives and picoline

By Reddy K.H.  

Transition Metal Chemistry, Vol. 25, Iss. 5, 2000-10 ,pp. : 505-510 (6)

Springer Publishing Company

Access to resources Recommend Favorite

Effect of the Thermal Decomposition and In Vitro Antimicrobial Activity of Mixed Ligand Copper(II) Complexes

By Kharadi G. J.  

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol. 42, Iss. 3, 2012-03 ,pp. : 424-431 (8)

Taylor & Francis Ltd

Access to resources Recommend Favorite

Interconversion of copper(II) to copper(I): synthesis, characterization of copper(II) and copper(I) 2,2′-biquinoline complexes and their microbiological activity

By Ali Basem F.   Al-Sou'od Khaldoun   Al-Ja'ar Nayef   Nassar Ahmad   Zaghal Mukarram H.   Judeh Zaher   Al-Far Rawhi   Al-Refai Mahmoud   Ibrahim Mohamad   Mansi Kamal   Al-Obaidi K. H.  

Journal of Coordination Chemistry, Vol. 59, Iss. 2, 2006-01 ,pp. : 229-241 (13)

Taylor & Francis Ltd

Access to resources Recommend Favorite

Schiff Base Polymers Obtained by Oxidative Polycondensation and Their Co(II), Mn(II) and Ru(III) Complexes: Synthesis, Characterization and Catalytic Activity in Epoxidation of Styrene

By Demetgül Cahit   Delikanlı Anıl   Sarıbıyık Oğuz Yunus   Karakaplan Mürüvvet   Serin Selahattin  

Designed Monomers & Polymers, Vol. 15, Iss. 1, 2012-01 ,pp. : 75-91 (17)

Taylor & Francis Ltd

Access to resources Recommend Favorite

Copper(II) and molybdenum(VI) complexes with 5-bromosalicylaldehyde S-allylisothiosemicarbazone: Syntheses, characterizations and crystal structures

By TAKJOO REZA   HASHEMZADEH ALIREZA   RUDBARI HADI AMIRI   NICOLÒ FRANCESCO  

Journal of Coordination Chemistry, Vol. 66, Iss. 2, 2013-01 ,pp. : 345-357 (13)

Taylor & Francis Ltd

Access to resources Recommend Favorite