Author： Jenner G.
Publisher： Taylor & Francis Ltd
ISSN： 0895-7959
Source： International Journal of High Pressure Research, Vol.22, Iss.3, 2002-01, pp. : 511-514
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Abstract
The pressure effect is examined in addition reactions of ketones (Knoevenagel reactions, formation of oximes and trichlorocarbinols). The sensitivity to pressure is enhanced with increasing size of the substituting groups of the carbonyl bond making the pressure parameter as a determining factor in sterically hindered reactions.
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