A-Z
- A
- B
- C
- D
- E
- F
- G
- H
- I
- J
- K
- L
- M
- N
- O
- P
- Q
- R
- S
- T
- U
- V
- W
- X
- Y
- Z
- 0-9
Classification
Publication

- Full text
- Title
- Author
- ISBN/ISSN
- Publisher
AdvancedSearch
- AdvancedSearch
- Search help

Simultaneous Analysis of the Rovibrational Levels υ₄=1, 2, and 3 of HCCI and DCCI Based on Infrared Spectra

Author： Sarkkinen H.

Publisher： Academic Press

ISSN： 0022-2852

Source： Journal of Molecular Spectroscopy, Vol.207, Iss.2, 2001-06, pp. : 136-142

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

The energy levels υ₄=1, υ₄=2, and υ₄=3 of DCCI have been analyzed by using the fundamental ν₄¹ (470–520 cm^-1) and the overtone 2ν₄⁰ (955–1005 cm^-1) bands together with the hot bands 2ν₄^0,2←ν₄¹, 3ν₄^1,3←2ν₄^0,2, and 3ν₄¹←ν₄¹. In the case of HCCI the previously studied hot bands connected to ν₄ have been completed by adding 3ν₄¹←ν₄¹ into the analysis. The various l-type resonances have been taken into account in the analyses of both the isotopomers. Furthermore, the Coriolis resonance between the close-lying ν₃ and ν₄ of DCCI has been considered. Altogether, accurate values for the molecular constants and the resonance parameters have been obtained from simultaneous analysis and they have been compared with those from separate analyses for different levels.

Related content

High-Resolution Infrared Spectra and Simultaneous Rovibrational Analysis of the ν₂, ν₃, ν₅, and ν₆Bands of H₃SiF

By Papoušek D. Bürger H. Rahner A. Schulz P. Hollenstein H. Quack M.

Journal of Molecular Spectroscopy, Vol. 195, Iss. 2, 1999-06 ,pp. : 263-280 (18)

Access to resources Recommend Favorite

Global Rovibrational Analysis of HCCNC Based on Infrared and Millimeter-Wave Spectra

By Vigouroux C. Fayt A. Guarnieri A. Huckauf A. Bürger H. Lentz D. Preugschat D.

Journal of Molecular Spectroscopy, Vol. 202, Iss. 1, 2000-07 ,pp. : 1-18 (18)

Access to resources Recommend Favorite

Simultaneous Analysis of Rovibrational and Rotational Spectra of the v 5 = 1 and v 8 = 1 Vibrational Levels of Propyne

By Pracna P. demaison J. Wlodarczak G. Lesarri A. Graner G.

Journal of Molecular Spectroscopy, Vol. 177, Iss. 1, 1996-05 ,pp. : 124-133 (10)

Access to resources Recommend Favorite

Simultaneous Rovibrational Analysis of the &ngr;₂, &ngr;₃, &ngr;₅, and &ngr;₆Bands of H₃¹³CF

By Papoušek D. Winnewisser M. Klee S. Demaison J. Pracna P.

Journal of Molecular Spectroscopy, Vol. 192, Iss. 1, 1998-11 ,pp. : 220-227 (8)

Access to resources Recommend Favorite

Simultaneous Rovibrational Analysis of the ν₂, ν₃, ν₅, and ν₆ Bands of H₃¹²CF

By Papoušek D. Pracna P. Winnewisser M. Klee S. Demaison J.

Journal of Molecular Spectroscopy, Vol. 196, Iss. 2, 1999-08 ,pp. : 319-323 (5)

Access to resources Recommend Favorite