Author： Zhang J. von Dreele R.B. Eyring L.
Publisher： Academic Press
ISSN： 0022-4596
Source： Journal of Solid State Chemistry, Vol.122, Iss.1, 1996-02, pp. : 53-58
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
The crystal structure of Pr 12 O 22 was determined utilizing Rietveld analysis of powder neutron diffraction data ( P 2 1 / c , a = 6.6850(2) A, b = 11.6004(4) A, c = 12.8271(4) A, beta = 99.974(1)#°, V = 979.67(8) A 3 ; total variables 130, R p = 3.25%, w R p = 5.02%). This structure is different from the models previously proposed, and the basic structural element is the isolated oxygen vacancy, as observed in another more-oxidized member of the R n O 2 n -2 series, Tb 11 O 20 .
Related content
By Harre N. Mercurio D. Trolliard G. Frit B.
European Journal of Solid State and Inorganic Chemistry, Vol. 35, Iss. 1, 1998-01 ,pp. :
Access to resources
Recommend
By Animitsa I. Dogodaeva E. Nokhrin S. Kosareva O. Neiman A.
Russian Journal of Electrochemistry, Vol. 46, Iss. 7, 2010-07 ,pp. :