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A New Nasicon-Type Phosphate Co_0.5Ti₂(PO₄)₃: I. Elaboration, Optical and Magnetic Properties

Author： Olazcuaga R. Dance J.M. Flem G.L. derouet J. Beaury L. Porcher P. Bouari A.E. Jazouli A.E.

Publisher： Academic Press

ISSN： 0022-4596

Source： Journal of Solid State Chemistry, Vol.143, Iss.2, 1999-03, pp. : 224-229

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

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Abstract

A new cobalt titanium monophosphate has been prepared by low temperature method. It crystallizes with the Nasicon-type structure. The indexation of the X-ray diffraction pattern is consistent with the R3 or the R32 space groups. The atomic arrangement is a three-dimensional framework formed by PO₄ tetrahedra sharing corners with TiO₆ octahedra. Co²⁺ is located in half of the antiprism M(1) sites in a centered (R3) or off- centered (R32) position. The optical, EPR and magnetic data can account for a pure ionic Co–O bond.

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