Author： Sirimanne P.M. Shirata T. Soga T. Jimbo T.
Publisher： Academic Press
ISSN： 0022-4596
Source： Journal of Solid State Chemistry, Vol.166, Iss.1, 2002-06, pp. : 142-147
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Abstract
A dye-sensitized solid-state cell was fabricated by sandwiching ruthenium bypridyl complex in between porous TiO2 and CuI films. Cis-dithiocyanate-bis(2,2′-bipyridyl -4-4′-dicarboxylate) ruthenium (II) exhibited excellent performance among the dyes tested for TiO2∣dye∣CuI cell. Different mechanisms are proposed for charge generation of the cell under different modes of illumination. A high incident photon to current conversion efficiency was observed under back wall illumination compared to that of front wall illumination. Dye molecules exhibited a relay effect under back wall mode illumination at wavelengths shorter than 400 nm.
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