Atomization Characteristic of Chromium on a Molybdenum Tube Atomizer by Electrothermal Atomic Absorption Spectrometry and Determination of Chromium in Biological Materials

Author： Ohta K. Uegomori H. Itoh S.I. Mizuno T.

Publisher： Elsevier

ISSN： 0026-265X

Source： Microchemical Journal, Vol.56, Iss.3, 1997-07, pp. : 343-351

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Abstract

Atomization characteristics of chromium have been studied by electrothermal atomic absorption spectrometry with a molybdenum tube atomizer. The appearance temperature ( T app ) of chromium nitrate was 1300#°C. The T app was independent of the heating rate of atomizer, but the temperature at the peak of the Cr AA signal increased with the heating rate. A sensitive absorption chromium signal was obtained in pure argon purge gas. The chromium signal decreased as the ratio of hydrogen in the purge gas increased. The optimal gas flow rate was Ar 480 ml min -1 + H 2 20 ml min -1 because of the avoidance of oxidation of the atomizer. The absolute characteristic mass (the mass of element giving 0.0044 abs.) of chromium by the atomizer was 0.35 pg and the detection limit was 23 pg ml -1 (3S/N). The interferences caused by large amounts of interferents were evaluated. The addition of thiourea served to eliminate the severe interferences. The accuracies of the recommended method were considered almost satisfactory for the determination of chromium in biological materials, compared with the certified values of NIST materials. The recovery of spiked chromium in biological materials was in the range from 93.5 to 102%.