The efficient and chemoselective MoO3-catalyzed oxidation of sulfides to sulfoxides and sulfones with H2O2

Author： Khodaei Mohammad M.   Bahrami Kiumars   Khedri Mohammad  

Publisher： NRC Research Press

ISSN： 1480-3291

Source： Canadian Journal of Chemistry, Vol.85, Iss.1, 2007-01, pp. : 7-11

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

Hydrogen peroxide together with MoO3 as catalyst can efficiently and chemoselectivity oxidize sulfides to sulfoxides and sulfones in the presence of other oxidized functional groups in ethanol at 50 °C in short reaction times.Key words: oxidation, sulfides, sulfoxides, sulfones, H2O2–MoO3 system.En opérant dans l'éthanol à 50 °C pour de courtes périodes, le peroxyde d'hydrogène en présence de MoO3 comme catalyseur peut oxyder d'une façon efficace et chimiosélective les sulfures en sulfoxydes et en sulfones, en présence d'autres groupes fonctionnels oxydés.Mots-clés : oxydation, sulfures, sulfoxydes, sulfones, système H2O2–MoO3.[Traduit par la Rédaction]

Related content

Polyvinylpolypyrrolidone-Supported Boron Trifluoride (PVPP-BF3): Highly Efficient Catalyst for Chemoselective Oxygenation of Sulfides to Sulfones by H2O2

By Mokhtary Masoud   Lakouraj Moslem Mansour   Niaki Masoumeh Rastegar  

Phosphorus, Sulfur, and Silicon and the Related Elements, Vol. 187, Iss. 3, 2012-03 ,pp. : 321-326 (6)

Taylor & Francis Ltd

Access to resources Recommend Favorite

Evaluation of the Catalytic Activity of H3PW12O40 in the Selective Oxidation of Sulfides to the Corresponding Sulfoxides or Sulfones

By Frenzel R.   Pizzio L.   Blanco M.   Sathicq G.   Romanelli G.  

Current Catalysis, Vol. 3, Iss. 2, 2014-08 ,pp. : 124-130 (7)

Bentham Science Publishers

Access to resources Recommend Favorite

Selective Oxidation of Sulfides to Sulfoxides and Sulfones Using n -Butyltriphenylphosphonium Dichromate (Bu n PPh 3 ) 2 Cr 2 O 7 in the Presence of Aluminium Chloride in Solution and Under Microwave Irradiation

By Mohammadpoor-Baltork Iraj   Memarian Hamid   Bahrami Kiumars   Esmayilpour Karim  

Phosphorus, Sulfur, and Silicon and the Related Elements, Vol. 180, Iss. 12, 2005-12 ,pp. : 2751-2766 (16)

Taylor & Francis Ltd

Access to resources Recommend Favorite

N‐Methylpyrolidin‐2‐one Hydrotribromide (MPHT) as a New and Efficient Reagent for the Oxidation of Sulfides to Sulfoxides and Sulfones

By Joseph Jomy   Jain Suman   Sain Bir  

Synthetic Communications, Vol. 36, Iss. 18, 2006-09 ,pp. : 2743-2747 (5)

Taylor & Francis Ltd

Access to resources Recommend Favorite

Selective Oxidation of Sulfides to Sulfones Using H2O2 and Anderson-Type Hexamolybdochromate(III) as Catalyst

By Supale Amit   Gokavi Gavisiddappa  

Phosphorus, Sulfur, and Silicon and the Related Elements, Vol. 185, Iss. 4, 2010-04 ,pp. : 725-731 (7)

Taylor & Francis Ltd

Access to resources Recommend Favorite