Dynamic criterion of the complex formation and the structure of molten halides: To the fortieth anniversary of the autocomplex model for the structure of melts

Author: Kirillov S.  

Publisher: MAIK Nauka/Interperiodica

ISSN: 1023-1935

Source: Russian Journal of Electrochemistry, Vol.43, Iss.8, 2007-08, pp. : 901-908

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Abstract

The results of my latest research into molten halides of alkali and alkaline-earth metals by a method of Raman spectroscopy are reviewed. A dynamic criterion for the formation of complexes in melts is considered. The results that testify to the existence of instantaneous and short-lived autocomplexes in these liquids are analyzed in the light of an autocomplex model for the structure of melts.