“Pattern recognition” from the UL emission spectra as a method for identifying the likeness and difference of uranium state in compounds

Author： Makarov L.   Solomennikov A.  

Publisher： MAIK Nauka/Interperiodica

ISSN： 1066-3622

Source： Radiochemistry, Vol.46, Iss.6, 2004-11, pp. : 536-544

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Abstract

The UL X-ray emission spectra of a wide range of uranium compounds were systematically studied. The chemical and isotope (233, 235, 238U) shifts in the L transitions were estimated. The suitability of these data for identifying the U state in real compounds and minerals was assessed. The experimental results were compared with the theoretical predictions based on the Hartree-Fock-Dirac method.

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