Structural Features of Triorganylantimony Dicarboxylates R3Sb[OC(O)R′)]2

Author： Sharutin V. V.   Sharutina O. K.   Pakusina A. P.   Platonova T. P.   Smirnova S. V.   Pushilin M. A.   Gerasimenko A. V.  

Publisher： MAIK Nauka/Interperiodica

ISSN： 1070-3284

Source： Russian Journal of Coordination Chemistry, Vol.29, Iss.11, 2003-11, pp. : 780-789

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

Triphenylantimony dibenzoate Ph3Sb(O2CPh)2, triphenylantimony bis(methylbenzoates) Ph3Sb(O2CC6H4Me-n)2 (n = 2, 4), and tri-p-tolylantimony bis(trichloacetate) p-Tol3Sb(O2CCCl3)2, whose Sb atoms have trigonal bipyramidal coordination, were studied using X-ray diffraction analysis. The Sb–O bond lengths are equal to 2.119(2) and 2.144(2); 2.115(2); 2.118(2) and 2.127(2); 2.133(2) Å, the Sb···O(=C) intramolecular contacts are equal to 2.797(2) and 2.698(2); 2.845(2); 2.814(2) and 3.030(2); 3.119(2) Å, respectively. The following correlation was found in the structures of triorganylantimony dicarboxylates: the shorter the Sb···O(=C) distances, the greater the equatorial angle on the side of the intramolecular contacts.

Related content

Synthesis and Structure of Tetraphenylantimony Phenoxyacetate and Ethylmalonate Ph4SbOC(O)R (R = CH2OPh and CH2C(O)OC2H5)

By Sharutin V. V.   Pakusina A. P.   Zadachina O. P.   Sharutina O. K.   Gerasimenko A. V.   Pushilin M. A.  

Russian Journal of Coordination Chemistry, Vol. 30, Iss. 6, 2004-06 ,pp. : 397-402 (6)

MAIK Nauka/Interperiodica

Access to resources Recommend Favorite

On the structural diversity anions coordinate to the butterfly-shaped [(R2Sn)3O(OH)2]2+ cations and vice versa

By Reuter Hans   Wilberts Hilko  

Canadian Journal of Chemistry, Vol. 92, Iss. 6, 2014-01 ,pp. : 496-507 (12)

NRC Research Press

Access to resources Recommend Favorite

(−)‐(2R,3R)‐O,O′‐Dibenzoyl‐(2R,3R)‐tartaric acid–hexa­methyl­phospho­ramide (1/2)

By  

Acta Crystallographica Section E, Vol. 63, Iss. 4, 2007-04 ,pp. : o1546-o1548 (NaN)

John Wiley & Sons Inc

Access to resources Recommend Favorite

High-Temperature Structural Disorder in R3NbO7

By Kovyazina S. A.   Perelyaeva L. A.   Leonidov I. A.   Bakhteeva Yu. A.  

Journal of Structural Chemistry, Vol. 44, Iss. 6, 2003-11 ,pp. : 975-979 (5)

Springer Publishing Company

Access to resources Recommend Favorite

Thermal and structural investigation of SnO2/Sb2O3 obtained by the polymeric precursor method

By de Melo Danniely   Santos M.   Santos Iêda   Soledade L.   Bernardi M.   Longo E.   Souza A.  

Journal of Thermal Analysis and Calorimetry, Vol. 87, Iss. 3, 2007-03 ,pp. : 697-701 (5)

Springer Publishing Company

Access to resources Recommend Favorite