Catalytic Effect of Reverse Micelles of a Cationic Surfactant on the Reaction of Calix[4]resorcinolarenes with 4-Nitrophenyl Bis(chloromethyl)phosphinate

Author： Zhil'tsova E. P.   Kudryavtseva L. A.   Timosheva A. P.   Kharitonov N. I.   Konovalov A. I.  

Publisher： MAIK Nauka/Interperiodica

ISSN： 1070-3632

Source： Russian Journal of General Chemistry, Vol.74, Iss.4, 2004-04, pp. : 627-631

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Abstract

The presence of the aminomethyl fragment in the calix[4]resorcinolarene molecule favors its phosphorylation in chloroform. Reverse micelles of (2-hydroxyethyl)dimethylpentadecylammonium bromide catalyze this reaction, the catalytic effect being dependent on the length of the hydrocarbon chain of a calixarene and detergent concentration.

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