Crystal Structure of the Complex of 1,2-Bis[2-(o-hydroxyphenoxy)ethoxy]ethane with Ammonium Thiocyanate

Author： Chekhlov A. N.  

Publisher： MAIK Nauka/Interperiodica

ISSN： 1070-3632

Source： Russian Journal of General Chemistry, Vol.74, Iss.7, 2004-07, pp. : 1038-1042

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Abstract

The complex of the podand 1'2-bis[2-(o-hydroxyphenoxy)ethoxy]ethane (L) with ammoniumthiocyanate, [NH4(SCN)L], was prepared, studied by single crystal X-ray diffraction. This is a host-guestcomplex; in its molecule the podand L is “wrapped” around the NH4+ cation, which forms hydrogen bondswith all the six oxygen atoms of the podand and one hydrogen bond with the sulfur atom of the SCN- anion. The geometric parameters (bond lengths, bond angles, torsion angles, etc.) of the molecule of [NH4(SCN)L] and packing of the molecules in the crystal were determined. The molecules are linked into infinite polymeric chains by intermolecular hydrogen bonds O-H···NCS.

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