Selenium-and tellurium-containing silatrane derivatives having an ECH2Si fragment (E = Se, Te)

Author： Sorokin M.   Voronkov M.  

Publisher： MAIK Nauka/Interperiodica

ISSN： 1070-3632

Source： Russian Journal of General Chemistry, Vol.76, Iss.3, 2006-03, pp. : 461-468

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

Previously unknown 1-(methylselenomethyl)-and 1-(phenyltelluromethyl)silatrane, bis(silatranylmethyl) selenide, bis(silatranylmethyl) telluride, bis(silatranylmethyl) diselenide, and dimethyl(triethoxysilylmethyl)telluronium, phenyl(silatranylmethyl)telluronium, methylbis(silatranylmethyl)selenonium, methylbis(silatranylmethyl)telluronium, and tris(silatranylmethyl)selenonium iodides were synthesized. The NMR spectra of these compounds, as well as of isostructural (methylchalcogenomethyl)triethoxysilanes, 1-(methylchalcogenomethyl)silatranes, the corresponding methylchalcogenonium iodides, methylorganyl(silatranylmethyl)chalcogenonium iodides, bis(trialkoxysilylmethyl) chalcogenides, and bis(silatranylmethyl) chalcogenides, in CDCl3, CD3OH, CD3CN, and DMSO-d 6 were studied.

Related content

Tellurium-containing Chalcogen Rings

By Taavitsainen Jari   Laitinen Risto  

Main Group Chemistry, Vol. 3, Iss. 1, 1999-07 ,pp. : 59-67 (9)

Taylor & Francis Ltd

Access to resources Recommend Favorite

Diorganyl Derivatives of Tellurium(IV) (-Telluranes of R 2 TeX 2 Type)

By Sadekov Igor D.   Zakharov Alexander V.   Maksimenko Alexander A.  

Sulfur Reports, Vol. 23, Iss. 2, 2002-01 ,pp. : 125-207 (83)

Taylor & Francis Ltd

Access to resources Recommend Favorite

Five-, six- and eight-membered ring organosilicon chalcogenides of the types Z2(SiMe2)2E (Z = Me2Si, H2C; E = S, Se, Te), Z(SiMe2E)2MR2 (Z = Me2Si, H2C, O; E = S, Se, Te; M = Si, Ge, Sn, R = Me, Ph) and (SiMe2ZSiMe2E)2 (Z = Me2Si, H2C; E = S, Se)

By Herzog Uwe   Böhme Uwe  

Silicon Chemistry, Vol. 2, Iss. 1-2, 2003-01 ,pp. : 77-92 (16)

Springer Publishing Company

Access to resources Recommend Favorite

Scaled quantum mechanical force fields for trifluoromethyl selenium derivatives. II. The (CF3)2Se and (CF3Se)2 molecules.

By Fernández L. E.   Varetti E. L.  

Canadian Journal of Chemistry, Vol. 87, Iss. 3, 2009-03 ,pp. : 507-513 (7)

NRC Research Press

Access to resources Recommend Favorite

Si3S-, Si3Se-, Si3Te-Bicyclo[1.1.0]butanes and Si3S2-Bicyclo[1.1.1]pentane

By Lee Vladimir Ya.   Miyazaki Shogo   Yasuda Hiroyuki   Sekiguchi Akira  

Phosphorus, Sulfur, and Silicon and the Related Elements, Vol. 186, Iss. 6, 2011-06 ,pp. : 1346-1350 (5)

Taylor & Francis Ltd

Access to resources Recommend Favorite