Mass-spectrometric fragmentation of N,N-dimethyl-4-methoxy-6-polynitromethyl-1,3,5-triazin-2-amines

Author: Bakharev V.   Gidaspov A.   Golovin E.  

Publisher: MAIK Nauka/Interperiodica

ISSN: 1070-3632

Source: Russian Journal of General Chemistry, Vol.77, Iss.6, 2007-06, pp. : 1104-1107

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Abstract

Mass-spectrometric fragmentation of N,N-dimethyl-4-methoxy-6-X-1,3,5-triazin-2-amine (X = fluorodinitromethyl, chlorodinitromethyl, bromodinitromethyl, trinitromethyl, 1,1-dinitroethyl, 2-hydroxy-1,1-dinitroethyl) under electron impact was studied. The stability of the molecular ion and the main fragmentation pathways are discussed.