Effect of reactant association on addition of tertiary amines to acrylic acid in aqueous solutions

Author： Malyshev A.   Shirshin K.   Kazantsev O.   Sivokhin A.   Zhiganov I.   Kuznetsov A.  

Publisher： MAIK Nauka/Interperiodica

ISSN： 1070-4272

Source： Russian Journal of Applied Chemistry, Vol.79, Iss.10, 2006-10, pp. : 1629-1633

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Abstract

The formation of betaines by the reaction of tertairy amines (N,N-dimethyl-N-2-hydroxyethylamine, N,N-dimethylaminoethyl methacrylate, N-methylmorpholine, N,N-dimethylaminopropionitrile, 1,4-diazabicyclo[2.2.2]octane) with acrylic acid in aqueous solutions in a wide concentration range was studied. The concentration effects observed were interpreted taking into account the association of the starting reagents.

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