Study of “ligand-free” catalytic systems with low palladium content for the Heck reaction

Author： Smirnov V.   Halaiqa A.   Shmidt A.  

Publisher： MAIK Nauka/Interperiodica

ISSN： 1070-4272

Source： Russian Journal of Applied Chemistry, Vol.83, Iss.3, 2010-03, pp. : 453-457

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

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Abstract

Effect of additives (reducing agent and tetraalkylammonium salt) on the course of the reaction of styrene arylation by bromobenzene (Heck reaction) in the absence of stabilizing ligands was studied. Conditions for effective catalysis of the reaction were found.

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