Verbanone in the synthesis of amidoketones from o-menthane series

Author： Koval’skaya S. Kozlov N. Tkachev A.

ISSN： 1070-4280

Source： Russian Journal of Organic Chemistry, Vol.42, Iss.8, 2006-08, pp. : 1141-1145

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Abstract

A verbanone reaction with acetonitrile under Ritter reaction conditions led to a selective formation of o-menthane derivatives, a mixture of stereoisomeric cis-and trans-8-acetamido-o-menthones. The streoisomers ratio depends on the reaction conditions and the character of acid catalyst used.

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