Features of reaction between fluorine-containing glycidyl ethers and alcohols in basic medium

Author： Bazhin D.   Gorbunova T.   Zapevalov A.   Kirichenko V.   Saloutin V.  

Publisher： MAIK Nauka/Interperiodica

ISSN： 1070-4280

Source： Russian Journal of Organic Chemistry, Vol.43, Iss.5, 2007-05, pp. : 656-659

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Abstract

The reaction of fluorine-containing glycidyl ethers with various alcohols (i-PrOH, MeOH, PhOH, 2,2,3,3-tetrafluoropropanol) in basic medium resulted in products of regioselective opening of the oxirane ring. In reaction of 2,2,3,3-tetrafluoropropyloxymethyloxirane with 2-propanol under conditions of phase-transfer catalysis the main product was the corresponding 1,2-diol (yield 42%).

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