Pressure dependence of photoluminescence in amorphous silicon nanopowder produced by plasmaenhanced chemical vapour deposition

Author: Costa J.   Roura P.   Sulimov N. A.   Sardin G.   Campmany J.   Morante J. R.   Bertran E.  

Publisher: Maney Publishing

ISSN: 1743-2847

Source: Materials Science and Technology, Vol.11, Iss.7, 1995-07, pp. : 707-710

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Abstract

The photoluminescence emission in silicon powder grown by plasma enhanced chemical vapour deposition has a very unusual dependence on pressure. Its intensity diminishes exponentially, IpL ∞ Io exp( − p/Po), where Po has a value of several pascals. Consequently it is detectable only under vacuum. This dependence is analysed within the framework of a multistep multiphoton excitation process. It is shown that an exponential dependence on pressure of the dynamic constants (lifetimes and optical cross-sections involved in the model) can account qualitatively for all the experimental results.MST/3288