

Author: Shchekotikhin A. Luzikov Yu. Buyanov V. Preobrazhenskaya M.
Publisher: Springer Publishing Company
ISSN: 0009-3122
Source: Chemistry of Heterocyclic Compounds, Vol.42, Iss.6, 2006-06, pp. : 746-752
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Abstract
Nucleophilic substitution of methoxy groups in 4,11-dimethoxynaphtho[2,3-f]indole-5,10-dione by the action of primary and secondary alkylamines, or arylamines leads to the formation of N-alkyl or N-aryl derivatives of 4,11-diaminonaphtho[2,3-f]indole-5,10-dione respectively. 4,11-Diamino-1H-naphtho-[2,3-f]indole-5,10-dione is obtained by the dealkylation of 4,11-bis[(1-phenylethyl)amino]-1Hnaphtho[ 2,3-f]indole-5,10-dione in the presence of a Lewis acid (BBr3).
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