Author： Straka M. Szatmáry L. Mareček M. Korenko M.
Publisher： Springer Publishing Company
ISSN： 0236-5731
Source： Journal of Radioanalytical and Nuclear Chemistry, Vol.298, Iss.1, 2013-10, pp. : 393-397
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
Electrochemistry of gadolinium and uranium in LiF–CaF2 (79–21 mol%) melt was studied using reactive Ni electrode and alloying reactions were observed. Deposits of gadolinium and uranium in the form of Gd–Ni and U–Ni intermetallic alloys were obtained after electrolysis by modulated current. Electrolysis of the same parameters was used also in the complex system of LiF–CaF2–UF4–GdF3 to demonstrate feasibility of selective deposition of uranium and therefore its separation from the system. Compact deposit of U–Ni alloy containing only traces of gadolinium was obtained.
Related content
Phase Diagram of the System LiF–NaF–CaF2–BaF2–BaMoO4
By Babaev B. D. Gasanaliev A. M.
Inorganic Materials, Vol. 39, Iss. 11, 2003-11 ,pp. :
Access to resources
Recommend
Glass formation in the ZrF4-PbF2-LaF3-NaF system
By Babitsyna A. Emel’yanova T. Fedorov V.
Inorganic Materials, Vol. 42, Iss. 1, 2006-01 ,pp. :
Recovery of LiF Chemiluminescence
By Glazunov O.O. Tsaregorodtsev Y.P.
Inorganic Materials, Vol. 37, Iss. 7, 2001-07 ,pp. :