Author： Polat K. Aksu M.L. Pekel A.T.
Publisher： Springer Publishing Company
ISSN： 0021-891X
Source： Journal of Applied Electrochemistry, Vol.30, Iss.6, 2000-06, pp. : 733-736
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
This study is concerned with the cathodic reduction of 4-nitroso-N,N-dimethylaniline to 4-amino-N,N-dimethylaniline in 1.0 M HCl and 1.0 M H_2SO_4 containing 10% MeOH. The effect of cathode material, supporting electrolyte, electroactive compound concentration, temperature and current density in the electrochemical synthesis of 4-amino-N,N-dimethylaniline were investigated. The best cathode material was tin, which gave a selectivity of 92.7% with a current yield of 90.3% at a current density of 6 mA cm^−2. The final electrolysis product was obtained as its respective HCl and H_2SO_4 salts and their structures were elucidated using spectrochemical techniques.
Related content
N‐(4‐Bromobenzylidene)‐2,4‐dimethylaniline
Acta Crystallographica Section E, Vol. 62, Iss. 10, 2006-10 ,pp. :
Access to resources
Recommend
By Roy P.R. Okajima T. Ohsaka T.
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 561, Iss. unknown, 2004-01 ,pp. :