Investigation of the Fiban K-1 Sulfocationite by the IR Spectroscopy Method

Author: Cherches B.K.   Lysenko G.N.   Egiazarov Y.G.  

Publisher: Springer Publishing Company

ISSN: 0021-9037

Source: Journal of Applied Spectroscopy, Vol.67, Iss.5, 2000-09, pp. : 806-811

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Abstract

Using the IR spectroscopy method, we have studied the state of water, sulfogroups, and adsorbed methanol in a Fiban K-1 fibrous cationite under different conditions of preparation of a sample. It is shown that on an air-dried cationite protonation of methanol is performed by the ionic pair [(H_2n+1O_n)^+·SO_3^−] after vacuum treatment at 20°C and by the ionic pair [H^+·SO_3^−] after vacuum treatment at 90°C.