Author： Dmitriev Y.A. Zhitnikov R.A.
Publisher： Springer Publishing Company
ISSN： 0022-2291
Source： Journal of Low Temperature Physics, Vol.122, Iss.3-4, 2001-02, pp. : 163-170
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Abstract
The paper is devoted to the problem of a matrix effect on symmetrization of EPR spectra of isolated organic radicals. By choice of proper matrices, there were realized, for CH_3 radicals, all cases of inner motion suppression, beginning from rigid CO matrix that hinders the fluctuations of C_3 rotation axes, and finishing by soft matrix of hydrogen allowing all types of molecular motion.
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