Reactionary processes during mechanical treatment of mixtures of ZnO and MnO2. I. Formation of defects and solid solution

Author: Kakazey Mykola   Vlasova Marina   Dominguez-Patiño Martha   Leon Ismael   Ristic Momcilo  

Publisher: Springer Publishing Company

ISSN: 0022-2461

Source: Journal of Materials Science, Vol.42, Iss.17, 2007-09, pp. : 7116-7122

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

Kinetics of defects formation, reaction process and formation of solid solution in powder mixtures of ZnO and MnO2 induced by prolonged mechanical treatment (MT) have been investigated (X-ray, FTIR, EPR). At MT in zones of deformation-destruction the different defects ( (I), (II), and (III) centers at all) are forming. The defects have various physical and chemical properties, and have different activation energies of annealing, Eact The part of these defects is responsible for the processes of hydration and carbonation of samples. In turn, the formation of defects is accompanied by development of various mechanothermical processes, which increase temperature of the sample, T MT, with the increasing of duration of MT, T MT. The increasing of T MT activates the reactionary processes: promotes a consecutive annealing the «low-temperature» defects having small values of Eact (I, II and III) and also leads to formation of Mn2+-doped Zn(OH)2. With the further increase of T MT, the process of MT is accompanied by an increasing of temperature of samples up to equilibrium, T eq and accumulation of “high-temperature” defects in the sample. As a result, in the sample the conditions for intensification of volumetric diffusion processes and formation of Mn2+-doped ZnO were created.