Role of titania in TiO2–SiO2 mixed oxides-supported metallocene catalyst during ethylene/1-octene copolymerization

Author: Jongsomjit Bunjerd   Ngamposri Sutti   Praserthdam Piyasan  

Publisher: Springer Publishing Company

ISSN: 1011-372X

Source: Catalysis Letters, Vol.100, Iss.3-4, 2005-04, pp. : 139-146

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Abstract

The present study showed enhanced activities of ethylene/1-octene copolymerization via TiO2–SiO2 mixed oxides-supported MAO with a zirconocene catalyst. It was proposed that titania was decorated on silica surface and acted as a spacer to anchor MAO to the silica support resulting in less steric hindrance and less interaction on the support surface.

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