Author： Zhou Weiyou Hu Bingcheng Sun Chengguo Xu Shichao Liu Zuliang
Publisher： Springer Publishing Company
ISSN： 1011-372X
Source： Catalysis Letters, Vol.141, Iss.11, 2011-11, pp. : 1709-1712
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Abstract
Efficient selective oxidation of cyclohexane to cyclohexanol and cyclohexanone catalyzed by metallodeuteroporphyrins with l-cysteine as the cocatalyst has been investigated. Apparently high catalytic activities of metallodeuteroporphyrins and selectivities of cyclohexanone were observed. The results could be attributed to the dual roles of l-cysteine as the axial ligand and the dehydrogenized reagent in the catalytic oxidation.Efficient selective oxidation of cyclohexane catalyzed by metallodeuteroporphyrins with l-cysteine as the cocatalyst have been investigated. l-cysteine could apparently improve the catalytic activities of metallodeuteroporphyrins and increase the selectivities of cyclohexanone.
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