Synthesis, Crystal Structure, and Characterizations of tetra(N-Benzoylmethyl-benzimidazole)dibromide cadmium(II) Complex: CdBr2(C7H5N2CH2COPh)4

Author： Jian Fangfang   Sun Pingping   Xiao Hailian   Zhao Pusu  

Publisher： Springer Publishing Company

ISSN： 1040-0400

Source： Structural Chemistry, Vol.16, Iss.6, 2005-12, pp. : 561-565

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Abstract

The structure of CdBr2(C7H5N2CH2COPh)4 has been determined by X-ray crystallography. It crystallizes in the tetragonal system, space group P4/N, with lattice parameters a = 14.904(3) Å, b = 14.904(3) Å, c = 11.817(2) Å, and Z = 2. The crystal structure consists of monomeric molecules of [CdBr2(C7H5N2CH2COPh)4] with distorted octahedron geometry for the CdBr2N4 chromophore. It is also characterized by elemental analysis, IR spectrum, electronic spectrum, and thermogravimetric-differential scanning calorimetry (TG-DSC).

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