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An Inorganic-Organic Hybrid Composite Featuring Metal-Chalcogenide Clusters

Author： Roland Bryan K. Flora Ware H. Carducci Michael D. Armstrong Neal R. Zheng Zhiping

Publisher： Springer Publishing Company

ISSN： 1040-7278

Source： Journal of Cluster Science, Vol.14, Iss.4, 2003-12, pp. : 449-458

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

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Abstract

The cluster complex, “Re₆(μ₃-Se)₈(PEt₃)₅(4-vinylpyridine)”(SbF₆)₂ (1), featuring the face-capped octahedral “Re₆(μ₃-Se)₈”²⁺ cluster core and site-differentiating triethylphosphine and 4-vinylpyridine ligands has been synthesized and structurally characterized. The complex crystallized in monoclinic space group P2₁ with a=11.748(1)Å, b=15.1212(2)Å, c=19.941(2)Å, α=90°, β=94.411(3)°, γ=90°, V=3531.8(7)Å³, Z=2, R1=0.0531, wR2=0.0774. Copolymerization of styrene with 1 via the polymerizable 4-vinylpyridine ligand afforded a novel inorganic-organic hybrid composite of high molecular weight and a low polydispersity index. Structural integrity of the cluster building block is maintained upon hybrid formation.

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