Author： Golubev V. Sen’ V.
Publisher： Springer Publishing Company
ISSN： 1066-5285
Source： Russian Chemical Bulletin, Vol.58, Iss.9, 2009-09, pp. : 1824-1827
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Abstract
The cation of 2,2,6,6-tetramethyl-1,4-dioxopiperidinium perchlorate disproportionates in acidic aqueous medium to give piperidinoxyl and/or 1-hydroxypiperidine, nitrone, and acetone. A mechanism of this reaction was proposed and the rate constants for its particular steps were calculated.
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