Carboranyl phosphites: the electronic effect in the Suzuki- Miyaura reaction

Author： Lyubimov S.   Verbitskaya T.   Rys E.   Petrovskii P.   Ilín M.   Davankov V.   Kalinin V.  

Publisher： Springer Publishing Company

ISSN： 1066-5285

Source： Russian Chemical Bulletin, Vol.59, Iss.8, 2010-08, pp. : 1665-1667

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Abstract

Isomeric carborane-containing phosphite ligands possessing different electronic properties have been synthesized. Their use in the Pd-catalyzed Suzuki-Miyaura reaction involving activated aryl bromides showed that phosphite with 9-o-carborane substituent has proved more efficient, with carboranyl phosphite having 1-m- carborane fragment being more efficient in the reactions with nonactivated aryl bromides.

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