Synthesis and characterization of Bis(μ-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V)]. Crystal structure of Mo2O2(Φ-S2)[S2P(OMe)2]2.C6H6

Author： Awwal L.   Bingham A.L.   Drake J.E.   Hursthouse M.B.   Light M.E.   Kumar R.   Ratnani R.  

Publisher： Springer Publishing Company

ISSN： 1074-1542

Source： Journal of Chemical Crystallography, Vol.36, Iss.2, 2006-02, pp. : 135-140

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

Bis(μ-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V) was prepared by dropwise addition of an ethanolic solution of the ammonium salt of O,O-dimethyldithio-phosphoric acid to a hot aqueous solution of MoCl5. The X-ray structure of Mo2O2(Φ-S2)[S2P(OMe)2]2.C6H6 was determined. Crystal data: Monoclinic, P21/n, a = 6.9788(6), b = 22.616(3), c = 14.633(1) Å, β = 101.193(9)°, V = 2265.5(4) Å−3, Z = 4. The immediate environment around the two molybdenum atoms is essentially square pyramidal if the Mo—Mo interaction is ignored. The terminal oxygen atoms are in the syn conformation.

Related content

Synthesis and crystal structure of [Ni(H2O)6](C19H17O9S)2·2H2O

By Zhang Zun-Ting   Zhang Xue-Ling   He Yun  

Journal of Chemical Crystallography, Vol. 36, Iss. 8, 2006-08 ,pp. : 517-522 (6)

Springer Publishing Company

Access to resources Recommend Favorite

Crystal Structure, Phase Transition and Thermal Behaviour of Dabcodiium hexaaquacopper(II) bis(selenate/sulfate), (C6H14N2)[Cu(H2O)6](S0.66Se0.34O4)2

By Nkhili Nouha   Rekik Walid   Naïli Houcine   Mhiri Tahar   Bataille Thierry  

Journal of Chemical Crystallography, Vol. 41, Iss. 11, 2011-11 ,pp. : 1680-1687 (8)

Springer Publishing Company

Access to resources Recommend Favorite

Synthesis and Crystal Structure of [Te{S(C6H3S)2O}]: A Tetracyclic Tellurium(II) Compound Displaying a Boat–Chair Conformation

By Martínez-Otero Diego   Alvarado-Rodríguez José   Andrade-López Noemí  

Journal of Chemical Crystallography, Vol. 40, Iss. 6, 2010-06 ,pp. : 531-535 (5)

Springer Publishing Company

Access to resources Recommend Favorite

Synthesis and Crystal Structure of Hydrate Adduct of 6-Benzylaminopurine and 5-Sulfosalicylic Acid [(C12H12N5)(C7H5O6S)·H2O]

By Xia Min   Ma Kui-Rong   Zhu Yulan  

Journal of Chemical Crystallography, Vol. 40, Iss. 7, 2010-07 ,pp. : 634-638 (5)

Springer Publishing Company

Access to resources Recommend Favorite

Crystal structure of bis 4-benzyl piperidinium monohydrogenmonophosphate pentahydrate, [C6H5CH2CHCH2CH2NH2CH2CH2]2HPO4·5H2O

By Elaoud Z.   Kamoun S.   Mhiri T.   Daoud A.   Driss A.  

Journal of Chemical Crystallography, Vol. 34, Iss. 5, 2004-05 ,pp. : 337-341 (5)

Springer Publishing Company

Access to resources Recommend Favorite