The soda-ash roasting of chromite ore processing residue for the reclamation of chromium

Author： Antony M. Tathavadkar V. Calvert C. Jha A.

ISSN： 1543-1916

Source： Metallurgical and Materials Transactions B, Vol.32, Iss.6, 2001-12, pp. : 987-995

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Abstract

Sodium chromate is produced via the soda-ash roasting of chromite ore with sodium carbonate. After the reaction, nearly 15 pct of the chromium oxide remains unreacted and ends up in the waste stream, for landfills. In recent years, the concern over environmental pollution from hexavalent chromium (Cr⁶⁺) from the waste residue has become a major problem for the chromium chemical industry. The main purpose of this investigation is to recover chromium oxide present in the waste residue as sodium chromate. Cr₂O₃ in the residue is distributed between the two spinel solid solutions, Mg(Al,Cr)₂O₄ and γ-Fe₂O₃. The residue from the sodium chromate production process was analyzed both physically and chemically. The compositions of the mineral phases were determined by X-ray diffraction (XRD), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). The influence of alkali addition on the overall reaction rate is examined. The kinetics of the chromium extraction reaction resulting from the residue of the soda-ash roasting process under an oxidizing atmosphere is also investigated. It is shown that the experimental results for the roasting reaction can be best described by the Ginstling and Brounshtein (GB) equation for diffusion-controlled kinetics. The apparent activation energy for the roasting reaction was calculated to be between 85 and 90 kJ·mol⁻¹ in the temperature range 1223 to 1473 K. The kinetics of leaching of Cr³⁺ ions using the aqueous phase from the process residue is also studied by treating the waste into acid solutions with different concentrations.