In situ electrochemical scanning probe microscopy corrosion studies on duplex stainless steel in aqueous NaCl solutions

Author: SCHMIDT-RIEDER E.   TONG X. Q.   FARR J. P. G.   AINDOW M.  

Publisher: Maney Publishing

ISSN: 0007-0599

Source: British Corrosion Journal, Vol.31, Iss.2, 1996-01, pp. : 139-146

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

Electrochemical scanning tunnelling microscopy and atomic force microscopy have been used to observe, in situ and in real time, the early stages of corrosion on duplex stainless steel in aqueous NaCl solution. With the specimens polarised in the transpassive region, the in situ techniques monitored clearly a process involving first a progressive etching of the damage layer, second the appearance of austenite and ferrite phases, and finally the formation of corrosion pits. A summary of these results is presented and the advantages and disadvantages of such in situ approaches are illustrated by comparing these observations with those obtained by ex situ examinations of the corroded specimen surfaces.

Related content