Recognition of α-Amino Acid from β- and γ-Amino Acid by N-Phosphorylation

Author： Jiang Yang   Zhong Ru-Gang   Tan Bo   Li Yan-Mei   Zhao Yu-Fen  

Publisher： Taylor & Francis Ltd

ISSN： 1042-6507

Source： Phosphorus, Sulfur, and Silicon and the Related Elements, Vol.178, Iss.4, 2003-04, pp. : 831-837

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Abstract

The reactivity of N-phosphoryl α-alanine differs from N-phosphoryl β-alanine and N-phosphoryl γ-amino butyric acid enormously. N-phospho-α-alanine could self-activate to yield N-phosphopeptides either in aqueous or nonaqueous media, but not β- or γ-amino acid analogues. The mechanism of the reaction is discussed.

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