Author: Veisi Hojat Ghorbani-Vaghei Ramin Eskandari Hosna Hemmati Saba Rezaei Ardashir Hajinazari Somaye Far Mohammad Raoof Heidari Entezari Azam
Publisher: Taylor & Francis Ltd
ISSN: 1042-6507
Source: Phosphorus, Sulfur, and Silicon and the Related Elements, Vol.186, Iss.2, 2011-02, pp. : 213-219
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Abstract
Poly-(N,N'-dibromo-N-ethyl-benzene-1,3-disulfonamide) (PBBS) and N,N,N',N'-tetrabromobenzene-1,3-disulfonamide (TBBDA) are good activators and catalytic reagents for the acetylation of alcohols, amines, and thiols. The presented method has the advantages of mild conditions, chemoselectivity, and good to high yields, and uses noncorrosive, inexpensive, recyclable, and environmentally friendly catalysts. We have also demonstrated that combining SiO2 with microwave energy provides an efficient, fast, convenient, and easy workup procedure for the synthesis of mono- and disubstituted acetates, acetamides, and thioacetamides. GRAPHICAL ABSTRACT[image omitted]
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