Clean Procedure for the Synthesis of α-Aminophosphonates Catalyzed by Biodegradable Ionic Liquid

Author: Fang Dong   Cao Yanfang   Yang Jinming  

Publisher: Taylor & Francis Ltd

ISSN: 1042-6507

Source: Phosphorus, Sulfur, and Silicon and the Related Elements, Vol.188, Iss.7, 2013-07, pp. : 826-832

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Abstract

A biodegradable SO3H-functionalized ionic liquid (IL) was prepared and used as the catalyst for a one-pot, three-component condensation synthesis of α-aminophosphonates from aldehydes, amines, and triethylphosphite/diethylphosphite at room temperature under solvent-free conditions or in aqueous media. The products could be simply separated from the reaction mixture and the catalyst could be recycled and reused for several times without noticeably reducing catalytic activity.

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