Short-range order in molecular liquids : evidence from neutron diffraction data of carbon tetrachloride and deuterochloroform

Author： Ireland P.R.   Mason R.   Rae A.I.M.  

Publisher： Taylor & Francis Ltd

ISSN： 1362-3028

Source： Molecular Physics, Vol.24, Iss.1, 1972-07, pp. : 17-22

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Abstract

A ‘perturbed crystal' model for short-range order provides quantitative agreement between observed and calculated neutron diffraction intensities from carbon tetrachloride and deuterochloroform. The nearest neighbour arrangement in CCl 4 is based on a cubic close packed structure and lies close to a minimum in the calculated intermolecular potential energy.

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