Asymptotic evaluation of multidimensional integrals for the S matrix in the semiclassical theory of inelastic and reactive molecular collisions

Author: Connor J.N.L.  

Publisher: Taylor & Francis Ltd

ISSN: 1362-3028

Source: Molecular Physics, Vol.25, Iss.1, 1973-01, pp. : 181-191

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

The asymptotic evaluation of multidimensional integrals for the S matrix in the semiclassical theory of inelastic and reactive molecular collisions is considered. The n -dimensional integral is assumed to possess two saddle points, whose position depends on a parameter and which may coalesce for a certain value of the parameter. A uniform asymptotic approximation is obtained by evaluating n -1 of the integrals by the ordinary non-uniform method of Chester et al. The resulting uniform asymptotic formulae are generalizations of the results for one dimensional integrals given in a previous paper.