Author： Lancelot G.
Publisher： Taylor & Francis Ltd
ISSN： 1362-3028
Source： Molecular Physics, Vol.31, Iss.1, 1976-01, pp. : 241-254
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Abstract
We present a theoretical and experimental investigation of the spin-orbit coupling mechanisms in sulphur-substituted nucleic acid components. If the sulphur 3 d orbitals take part in &pgr;-electron configuration, new spin-orbit coupling paths appear. We have studied the phosphorescence of sulphur-containing pyrimidines and purines at 77 K and in the range 1·42–4·2 K.
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