Author： Jørgensen Chr.
Publisher： Taylor & Francis Ltd
ISSN： 1362-3028
Source： Molecular Physics, Vol.4, Iss.3, 1961-05, pp. : 235-239
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
While the effect of rubidium and caesium ions in solid salts of IrCl 6 -- is a shift to lower wave-numbers, comparable to that occurring in organic solvents relative to water, the dark blue silver (I) and thallium (I) salts have a new, broad band in the red. Mixed crystals of Cs 2 IrCl 6 and Tl 2 IrCl 6 are prepared, and the absorption spectra are discussed in terms of a tendency to ‘ferroelectric rattling' and strong covalent bonding of Ag and Tl. Analogous cases are pointed out in solid salts of other 5 d -hexahalides.
Related content
Access to resources
Recommend
Journal de Physique, Vol. 30, Iss. 7, 1969-07 ,pp. :
Line broadening in the Si I, Si II, Si III, and Si IV spectra in the helium plasma
Astronomy & Astrophysics, Vol. 508, Iss. 1, 2009-12 ,pp. :
SUPERCONDUCTIVITY I N ALKALI TUNGSTEN BRONZES
Le Journal de Physique Colloques, Vol. 39, Iss. C6, 1978-08 ,pp. :
Contribution to the study of F-centres in alkali halides.
Journal de Physique et le Radium, Vol. 15, Iss. 5, 1954-05 ,pp. :