Author： Golding R.M. Pascual R.O.
Publisher： Taylor & Francis Ltd
ISSN： 1362-3028
Source： Molecular Physics, Vol.41, Iss.2, 1980-10, pp. : 421-428
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Abstract
A method is developed whereby the effect of vibronic coupling on the N.M.R. chemical shift in a transition metal ion paramagnetic system may be explored. The specific case of a d 1 transition metal ion vibrating in a strong crystal field of octahedral symmetry is examined. The results show that in certain regions within the paramagnetic system vibronic coupling may affect significantly the N.M.R. chemical shifts.
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