L.M.R. observation of the sulphur hydride free radical SD in its X 2 Π 3/2 ground state

Author: Zeitz D.   Bohle W.   Werner J.   Hinz A.   Urban W.  

Publisher: Taylor & Francis Ltd

ISSN: 1362-3028

Source: Molecular Physics, Vol.54, Iss.4, 1985-03, pp. : 953-958

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Abstract

By employing a mid-infrared laser magnetic resonance (L.M.R.)-spectrometer the fundamental vibrational rotational band of SD in its X 2 Π 3/2 ground state has been observed. The band origin &ngr; 0 = 1885·9114(2) cm -1 and the rotational constants B e = 4·95130(3) cm -1 and &agr; e = 0·10308(1) cm -1 were determined.